Spin state modulation of iron spin crossover complexes via hydrogen-bonding self-assembly.
نویسندگان
چکیده
Iron complexes derived from 6-diaminotriazyl-2,2'-bipyridines display spin crossover behaviour, and hydrogen bonding-controlled self-assembly with a suitable barbiturate partner can modulate the crossover from mixed low and high spin to high spin. This system is the first to use solution-phase self-assembly of complementary hydrogen-bonding organic species to modulate spin state.
منابع مشابه
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عنوان ژورنال:
- Chemical communications
دوره 49 56 شماره
صفحات -
تاریخ انتشار 2013